Hydrogen bonding between solid and liquid phases?
I have been reading this paper on a 'switch-on' fluorophore that only fluoresces when in a solution of water (through hydrogen bonding). Assuming the fluorophore was in a solid phase with liquid water in contact with the solid, could hydrogen bonding occur between the two phases?
I'm struggling to find any academic papers that prove/disprove this phenomenon so any pointers would be greatly appreciated!
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︎ Apr 01 2020
SolidβPhase Radical Polymerization of Halogen BondingβBased Crystals and Applications to PreβShaped Polymer Materials
Liquid vinyl monomers were converted to solid crystals via halogen bonding and underwent solidβphase radical polymerizations through heating at 40 Β°C or ultraviolet photoβirradiation (250β385 nm). The Xβray crystallography analysis showed the high degree of monomer alignment in the crystals. The polymerizations of the solid monomer crystals yielded polymers with high molecular weights and relatively low dispersities because of the high degree of the monomer alignment in the crystal. As a unique application of this system, the crystalized monomers were assembled to preβdetermined structures, followed by solidβphase polymerization, to obtain a twoβlayer polymer sheet and a threeβdimensional houseβshaped polymer material. The twoβlayer sheet contained a unique asymmetric pore structure and exhibited a solventβresponsive shape memory property and may find applications to asymmetric membranes and polymer actuators.
https://ift.tt/2wdIRgs
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︎ Mar 17 2020
[ASAP] Supramolecular Modulation of Hybrid Perovskite Solar Cells via Bifunctional Halogen Bonding Revealed by Two-Dimensional 19F Solid-State NMR Spectroscopy
Journal of the American Chemical SocietyDOI: 10.1021/jacs.9b13701
https://ift.tt/2FDgPff
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︎ Jan 09 2020
Made a homemade foundry with my 17yo son today. Including watching some DIY videos, shopping for parts and finally smelting, we spent 12 hours of solid bonding time together. One of the best days of my life. (/r/Bladesmith)
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︎ Nov 19 2017
James Bond style Metal Gear Solid 3 Poster
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︎ Dec 18 2019
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︎ Jan 10 2020
Bonding with fellow Redditors from my small hometown in MI (round 2 with cropped image)
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︎ Mar 13 2020
This picture was taken somewhere on the Indian highway where two elephants reach out to each other in a brief moment of love and bonding before being separated from each other for a lifetime of serving man......
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︎ Jul 01 2019
Unpopular Opinion: Octopussy is a solid Bond film that would have done even better had it been titled βProperty of A Ladyβ
I also want to add that Gobinda was such a charismatic henchman, with a royal Sikh look and a great personality.
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︎ Jan 20 2020
Waited 2 hours, ended up bonding with a Void Elf talking in Thalassian to cure the boredom. GTZ <3
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︎ Jan 24 2020
[WTS] KABATIME XXL: vintage Omega, Universal Geneve, Jaeger-LeCoultre, Breitling, Longines, Zenith, Tissot, divers, ... - Many Seamasters, blue dials, sparkle & linen dials, solid gold 18k 14k, Futurematic, Constellation, Kontiki, Seamaster 120, Bond, ...
imgur.com/a/ocMGgZr
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︎ Jul 19 2019
[SALE] KABATIME XXL: vintage Omega, Tudor, IWC, Universal Geneve, Jaeger-LeCoultre, Breitling, Longines, Zenith, Tissot, divers, ... - Many Seamasters, blue dials, sparkle & honeycomb dials, solid gold 18k 14k, Futurematic, Constellation, Polerouter, Seamaster 120, Bond, WWW Dirty Dozen, 6B/159, HS8
imgur.com/a/eYoxEWY
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︎ Sep 13 2019
LPT: Learn an uncommon foreign language with your spouse, like Italian, Danish, etc. Not only will this be a fun bonding experience, but you can also discuss personal topics in public without worrying about others eavesdropping.
Recently did this to discuss negotiating the purchase of a car with my wife in front of the sales person. He had no clue what we were saying and had the upper hand since we were able to adjust our tactics in the moment.
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︎ Feb 24 2020
Solid Snake vs. James Bond, except instead of fighting they switch places. Who does better?
The composite version of Solid Snake and James Bond switch places - Solid Snake has to go through all of the Bond movies, while Bond has to go through every game Solid Snake has starred in, taking over his role. They get whatever equipment the movie/game gives them.
Who does better overall? Where - if at all - do they fail?
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︎ Feb 20 2020
[WTS] KABATIME XXL: vintage Omega, Tudor, IWC, Universal Geneve, Jaeger-LeCoultre, Breitling, Longines, Zenith, Tissot, divers, ... - Many Seamasters, blue dials, sparkle & linen dials, solid gold 18k 14k, Futurematic, Constellation, Kontiki, Polerouter, Seamaster 120, Bond, ...
imgur.com/a/Ze2jtmo
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︎ Jul 27 2019
Dexter hates bath houses, so before cage cleaning time I'll let him bathe on his cage floor. Also giving him some alfalfa to help with bonding :) I held the dust in my hand at first too and he dug it out of my hand lol
v.redd.it/8br9a5vop0r41
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︎ Apr 05 2020
[SALE] KABATIME XXL: vintage Omega, Universal Geneve, LeCoultre, IWC, Breitling, Longines, Zenith, Tissot, divers, ... - Many Seamasters, blue dials, sparkle & linen dials, solid gold 18k 14k, Futurematic, Constellation, Kontiki, Bond, ...
imgur.com/a/d2i5XWu
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︎ Jul 08 2019
[Batchelor] Apparently, rumblings out of the #Canucks room are that Thatcher Demko has never seen a horse in the flesh prior to yesterdayβs team bonding session at a Dude Ranch in Banff.
twitter.com/BatchHockey/sβ¦
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︎ Oct 04 2019
Father-in-Law took me out to 500+ yards this weekend. Nothing too crazy but it was a great bonding experience with the old man.
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︎ Jan 13 2020
[SALE] KABATIME XXL: vintage Omega, Tudor, IWC, Universal Geneve, Jaeger-LeCoultre, Breitling, Longines, Zenith, Tissot, divers, ... - Many Seamasters, blue dials, sparkle & linen dials, solid gold 18k 14k, Futurematic, Constellation, Kontiki, Polerouter, Seamaster 120, Bond, ...
imgur.com/a/Ze2jtmo
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︎ Jul 27 2019
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︎ Mar 06 2020
[Video] Filmed through TikTok, in a boys locker bathroom, a bunch of kids sing a sea shanty as old as time. Replaying a history of bonding through song
vm.tiktok.com/dqk7a8/
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︎ May 30 2019
My Dad is Yoshikage Kira Part 10: Father and son bathroom bonding session prank gone wrong. (not in a sexual way)
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︎ Dec 06 2019
I run a number of projects alongside each other depending on where I am in the house. This is one of my bonding squares that go to a local NICU that helped my daughter when she was born. So simple but lovely to do to relax in bed at night
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︎ Mar 11 2020
Common knowledge to alot, new info for some. How plastic glue bonds your models together. It melts and welds separate parts into one solid piece.
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︎ Feb 12 2019
Water found in a habitable super-Earth's atmosphere for the first time. Thanks to having water, a solid surface, and Earth-like temperatures, "this planet [is] the best candidate for habitability that we know right now," said lead author Angelos Tsiaras.
astronomy.com/news/2019/0β¦
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︎ Sep 11 2019
This picture was taken somewhere on the Indian highway where two elephants reach out to each other in a brief moment of love and bonding before being separated from each other for a lifetime of serving man......
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︎ Jul 01 2019
Of all the antagonists in "Future", she's the one I can't see, in ANY WAY, even after her "defeat", bonding with Steven/having fun with the CG...I can even see Jasper starting to warm up, but for our lil "manager"? It just won't fit her character; how do you think she'll go out of the picture?
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︎ Nov 09 2019
NJDevils have started practice in Annapolis. Ty Smith is not on the ice. Everyone else is. He did travel here with the team yesterday/take part in the sailing team bonding exercise.
twitter.com/cmasisak22/stβ¦
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︎ Sep 30 2019
Why don't most solid materials readily bond?
Take two peices of sheet metal (ionic bonds) and lay them on top of one another, they don't bond.
I imagine there is difference in energy states between the electrons of two bonded atoms vs. two adjacent non bonded atoms but I was hoping someone could shed some more light on this. Also, which pair has a lower energy state? The two bonded atoms or non bonded atoms?
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︎ May 07 2019
'Bernie Blackout' Strikes Again? Despite Iowa Poll Average Showing Sanders in Solid 2nd, CNN Uses Old Poll to Show Him in 4th
commondreams.org/news/201β¦
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︎ Dec 23 2019
This picture was taken somewhere on the Indian highway where two elephants reach out to each other in a brief moment of love and bonding before being separated from each other for a lifetime of serving man......
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︎ Jul 02 2019
Pro Tip: On those long days when you have no time for bonding or hedgie interaction, turn the heat up the bathroom, throw your baby in a playpen, and enjoy a nice, well deserved bath. My little dude loves it.
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︎ Feb 06 2020
Just finished the bonding chapter in Winterβs Heart... why tf am I crying in the club
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︎ Jul 08 2019
A woman approached me in the park today selling artwork to support cPTSD awareness. I told her I have cPTSD too and we had a moment bonding over how creatively expressing your emotions is so important if you can manage. WAY TO GO, I was so proud of a fellow survivor having the bravery to open up.
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︎ Apr 08 2019
This is Pan! We got him Sunday. Today is the second day in a row he's fallen asleep on me for after-dinner bonding. I'd say things are going well (,:
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︎ Mar 05 2020
I painted some lesbian mermaids bonding during quarantine. (If you want to read the story behind them, Iβll drop the link in the comments).
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︎ Mar 17 2020
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︎ Feb 17 2019
Women have chemicals which facilitate bonding with their infant. Men's bodies don't have this chemical, right? So how do men bond with children, or do men not bond in the same way?
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︎ Jan 06 2020
Solid praise for the new Bond film
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︎ Aug 20 2019
How can a chemist unambiguously distinguish between a long-range intermolecular interaction or an exceptionally long range bond in a solid material?
Consider the following example from a crystallography experiment: A sulfur atom is bound to three additional atoms in trigonal pyramidal geometry. However, it is aligned in the three dimensional structure between two additional atoms. The distance is longer, but the interactions "line up" such that it would yield trigonal bipyramidal geometry. How would one distinguish whether the long bonds were covalent or noncovalent interactions?
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︎ Mar 01 2014
Calling all Skyline and/or Stagea owners! Is this a normal repair on the front strut towers or has it been covered up? None of the new metal plates are exposed, instead there is a thick layer of flexible repair bonding. Is this normal to prevent it from corrosion in the future after a repair?
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︎ Dec 04 2019
[SALE] MOTHER'S DAY DISCOUNT SALE: LADIES VINTAGES: Omega, Cartier, Tudor, Jaeger-LeCoultre, Breitling - Rare sparkle dials, blue meteorite dial, Seamaster Bond, 18k solid gold, tank, sparkle, sunburst, Seamaster, Geneve, blue, box, rectangles,...
imgur.com/a/OYExVhA
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︎ May 02 2019
Box Office Week - Terminator: Dark Fate takes #1 with an awful $29M on a $185M+ budget. Harriet opens solid at #4 with $12M. Motherless Brooklyn bombs at #9 with $3.6M. Arctic Dogs has the worst opening for a film in over 2,8000 theaters at #10 with $3.1M.
Rank |
Title |
Domestic Gross (Weekend) |
Worldwide Gross (Cume) |
Week # |
Percentage Change |
Budget |
1 |
Terminator: Dark Fate |
$29,000,000 |
$123,600,000 |
1 |
N/A |
$185M - $196M |
2 |
Joker (2019) |
$13,925,000 |
$934,011,992 |
5 |
-28% |
$55M |
3 |
Maleficent: Mistress of Evil |
$12,175,000 |
$383,224,711 |
3 |
-37% |
$185M |
4 |
Harriet |
$12,000,000 |
$12,000,000 |
1 |
N/A |
$17M |
5 |
The Addams Family (2019) |
$8,499,007 |
$129,295,007 |
4 |
-29% |
$40M |
Films Reddit Wants to Follow
This is a segment where we keep a weekly tally of currently showing films that aren't in the Top 5 that fellow redditors want updates on. If you'd like me to add a film to this chart, make a comment in this thread.
Title |
Domestic Gross (Weekly) |
Domestic Gross (Cume) |
Worldwide Gross (Cume) |
Budget |
Week # |
Toy Story 4 |
$80,521 |
$433,885,761 |
$1,070,882,919 |
$200M |
20 |
Once Upon a Time in Hollywood |
$866,275 |
$140,738,793 |
$367,579,072 |
$90M |
15 |
Parasite |
$2,636,746 |
$7,554,256 |
$108,051,425 |
$11M |
4 |
Jojo Rabbit |
$1,425,812 |
$4,286,236 |
$4,857,708 |
UNK |
3 |
The Lighthouse |
$4,398,648 |
$6,999,135 |
$6,999,135 |
UNK |
3 |
Notable Film Closings
Title |
Domestic Gross (Cume) |
Worldwide Gross (Cume) |
Budget |
Spider-man: Far From Home |
$390,532,085 |
$1,131,783,353 |
$160M |
As always r/boxoffice is a great place to share links and other conversations about box office news.
Also you can see the archive of all Box Office Week posts at r/moviesboxoffice (which have recently been updated).
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︎ Nov 04 2019
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︎ Jan 30 2020
This cannot be overstated: You can literally DOUBLE the amount of quality time and the number of precious bonding experiences you will have with your children and spouse (or parents/siblings/friends) in your life by just not being mormon. DOUBLE the time and experiences. Itβs called sunday-funday.
Stated another way, you are squandering HALF of the quality time you could have with your children during those precious years they are with you by spending it all at church and in meetings and doing mormon shit to make the mormon corporation operate. Or you are wasting a full HALF of the time you could have with your spouse/partner to just be a couple however you want to spend it. Or hell, you are just squandering the time you could have for yourself, your self-development or mental and physical health or hobbies or fun. Such a sad waste.
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︎ Mar 17 2019
Bonding time, keeping each other warm on a cold winter day in Shanghai
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︎ Feb 19 2020
Asshole cat ruins night by not being an asshole. My cat normally runs from me. Tonight of her own freewill she laid down in my lap. She has been like this for over an hour. I have so many things I need to do like eat and oh yeah π©. I might poop my pants just to enjoy this bonding moment. π
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︎ Dec 11 2019
Bonding brothers. The amount of time they spend in bed is crazy
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︎ Feb 28 2020
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︎ Oct 17 2019
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