Bromobenzene with NH2- or chlorobenzene with NH2-? I'm thinking bromobenzene because bromine is a better leaving group that would better promote the formation of the benzyne intermediate but I'm not totally sure.
Is it possible to Convert Tianeptine FAA into Iodo-tianeptine via simple addition of iodine the usual reaction.?
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At first glance the E1 product seems like the major product, but I believe something more interesting would happen:
https://preview.redd.it/edmr27f2ln081.png?width=632&format=png&auto=webp&s=52f5e74c226de9bba700ae15c2c82e5ee83b3b1c
I would think itβs a Sn1 reaction because thatβs what my book says and the O is being replaced with an NH group. But according to other sources Iβve read it is a nucleophilic addition reaction.
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The precision shot poison effect of Le Monarque is already pretty great when doing ad-clear, but having the Chain Reaction also deal poison damage would be phenomenal. It's already a great feeling bow and I feel like this wouldn't be too game-busting compared to some other ad-clearing options out there (looking at you Trinity Ghoul!).
Alternatively, also increasing the poison damage or tick rate wouldn't go amiss either; mostly to help do more chunk damage to target with more health than your average red-bar.
Additional information: I was wondering if it is possible to obtain the enolate and let this react with itself (provided it has a ketone and aldehyde group present). No catalyst is added as the enolate would be formed during the 1,4-addition.
Sorry for any grammar mistakes, English is not my native language.
Another youtube video about addition reactions to alkenes.
We go over:
- Markovnikov Rule
- Anti-Markovnikov Rule
- Hydration of Alkenes
- Hydrogenation of Alkenes
- Dihydroxylation of Alkenes (Osminium Tetroxide)
- Dihydroxylation of Alkenes (Potassium Permanganate, Cold )
- Oxidative Cleavage (Potassium Permanganate, Warm)
- Oxidative Cleavage (Ozonolysis)
Here's the podcast format as well.
Have a great weekend!
I mean, when i was younger (I mean like 4 - 8) I often got 'bullied' for being "girlish", honestly, my favourite colour was pink, I had long hair, what did you expect kids that grew up being told that they can't be feminine to say to me? But anyway, it wasn't that.. bad, honestly. Well, for me it was. I cut my hair (by myself) and started to hate pink. It really had an effect on me. I was a very shy, introverted (well, i still am tbh), antisocial kid, so i guess that's why it got to me easily.
But it still wasn't that bad, the other kids didn't physically abuse me (with.. very phew exceptions), it was just calling names and casting me out. I shouldn't be this affected by this. It had a massive effect on my life though, it made me reject anything if I realised it would be "girlish", if only I didn't, maybe I would have found out about my gender earlier.. oh well..
Lightning story time! I once wore nail polish to school, not realising it was a feminine thing. Im sure you can imagine what happened next :)
Funny how my mum always liked it when I did or liked more feminine things, like nail polish or long hair, but then screamed at me when I came out...
I just.. i dont know, my story isn't that bad, especially compared to some of your stories. I just feel like an attention seeking little bitch, and yet, here I am telling my story. Its odd how much tiny things can affect little kids..
If you read all this.. uh.. I appreciate it, honestly. But, why?
Edit: oh and, just in case someone read all this and is gonna comment. Please note that I am NB, so please don't call me "girl" or something like that ;-; thanks :D
I don't see why not but I never though to think of it that way.
Does anyone have any good links or maybe tips for learning what to look for in order to determine major product when given random molecules with different reagents and nucleophiles/bases? The way I understand it, it feels like every reagent/reaction just needs to be memorized to correctly determine which addition reaction (hydrohalogenation, hydroboration, etc) to follow. Iβm already not the best at chemistry, so any links/explanations you guys give would be huge. Thanks!
So my understanding for the first problem is that the hydrogen substituent should be added in a way which makes the resultant stereocenter S designation. I'm pretty sure I did that but I'm told that two of these are wrong. For the second part, I believe the point is to assign priority based on what the molecule will look like after it loses the double bond but before the addition, and then designate the incoming hydrogen as a wedge if we are already looking at the Re face and a dash if we are looking at the Si one. Is my reasoning wrong or is the answer key wrong?
https://preview.redd.it/3arqw2srm1571.jpg?width=3024&format=pjpg&auto=webp&s=e925473075d3e75f4dd82e4ff5488c8f2ce7d260
Is it possible to Convert tianeptine FAA into Iodo-tianeptine via simple addition of iodine the usual reaction.?
Another youtube video about addition reactions to alkenes.
We go over:
- Markovnikov Rule
- Anti-Markovnikov Rule
- Hydration of Alkenes
- Hydrogenation of Alkenes
- Dihydroxylation of Alkenes (Osminium Tetroxide)
- Dihydroxylation of Alkenes (Potassium Permanganate, Cold )
- Oxidative Cleavage (Potassium Permanganate, Warm)
- Oxidative Cleavage (Ozonolysis)
Here's the podcast format as well.
Have a great weekend!
