Hey everyone! As the title says I recently started collecting KC vinyls and pretty much planned to go through their discography based on what I listen to the most. I was fortunate enough to get an original pressing of ITCotKC from my dad, along with a slightly newer (90s?) pressing of Larks.
My main question is this: did KC release Radical Action (to Unseat the Hold of Monkey Mind) in vinyl form? I really like that entire album and can't seem to find any online, I might just not be looking hard enough though. Any help is appreciated!
As the title says I don’t know if there is any official release of Radical on vinyl. The only thing I found is this but it says it’s an unofficial release.
A photocatalytic system was developed for perfluoroalkylation of vinyl‐substituted all‐carbon quaternary centers by using perfluoroalkyl halides with concomitant 1,2‐aryl migration. This strategy possesses good functional‐group compatibility and can serve as a powerful synthetic tool for the construction of valuable perfluoroalkylated compounds that would be difficult to prepare by other methods.
Abstract
An efficient method for photocatalytic perfluoroalkylation of vinyl‐substituted all‐carbon quaternary centers involving 1,2‐aryl migration has been developed. The rearrangement reactions use fac‐Ir(ppy)3, visible light and commercially available fluoroalkyl halides and can generate valuable multisubstituted perfluoroalkylated compounds in a single step that would be challenging to prepare by other methods. Mechanistically, the photoinduced alkyl radical addition to an alkene leads to the migration of a vicinal aryl substituent from its adjacent all‐carbon quaternary center with the concomitant generation of a C‐radical bearing two electron‐withdrawing groups that is further reduced by a hydrogen donor to complete the domino sequence.
https://ift.tt/3bRAYh2
Journal of the American Chemical SocietyDOI: 10.1021/jacs.0c09289
Masato Miyajima, Kotaro Satoh, Takahiro Horibe, Kazuaki Ishihara, and Masami Kamigaito
https://ift.tt/317c2Oz
Cascade formation of two C−C bonds at an electron‐rich alkene is made possible by sequential capture of a radical (by intermolecular addition) and an anion (by intramolecular aromatic substitution), each formed in the photoredox cycle from the same organic photocatalyst.
Abstract
We report tandem alkyl‐arylations and phosphonyl‐arylations of vinyl ureas by way of a photocatalytic radical‐polar crossover mechanism. Addition of photoredox‐generated radicals to the alkene forms a new C−C or C−P bond and generates a product radical adjacent to the urea function. Reductive termination of the photocatalytic cycle generates an anion that undergoes a polar Truce–Smiles rearrangement, forming a C−C bond. The reaction is successful with a range of α‐fluorinated alkyl sodium sulfinate salts and diarylphosphine oxides as radical precursors, and the conformationally accelerated Truce–Smiles rearrangement is not restricted by the electronic nature of the migrating aromatic ring. Formally the reaction constitutes an α,β‐difuctionalisation of a carbon–carbon double bond, and proceeds under mild conditions with visible light and a readily available organic photocatalyst. The products are α,α‐diaryl alkylureas typically functionalized with F or P substituents that may be readily converted into α,α‐diaryl alkylamines.
https://ift.tt/3aFRI9T
My pi and I are pursuing a new route to our polymer. Particularly transitioning from condensation polymerization to vinyl based. Our group is small and i haven't much experience with radical polymerization. I'm wondering if there is any insight here for radical polymerization of ion containing monomers. Particularly, to achieve high molecular weight you need to dilute as the ionic polymer becomes very viscous. Solvent will likely result in chain transfer and disproportionate which will kill the polymerization. Does anyone have experience getting around this? I am looking for any general insight or good references to learn more about acceptable additives and polymerization modifications for vinyl based monomers
*FINAL EDIT* So we miscalculated the response for this and we will no longer will be taking orders. We appreciate the IMMENSE support in helping a small local shop keep doing what we love for almost 30 years! If you ever find yourself in Philly, come see us at Main St. Music. Happy RSD everyone!
*EDIT 2* Hey everyone! Thanks again for all the awesome feedback. Between all the craziness I seem to have missed/possibly deleted someone's chat that made an order, can DIBS M. hit us back up? Just respond back with your full name and your order so we can confirm your paypal payment. Store opens at 12 so we will be getting back to you all around then. Thanks you!
*EDIT* Hey guys store is closing so we will get back to you guys in the morning! Thank you for everyone who has ordered!
Hey everyone! This is a first for us but we wanted to bring our left overs to the Vinyl Collectors community at retail prices! No need for finding fees or dealing with scalpers! Let us know what you are interested in and we will total you up. 8% Philly tax + shipping ($4 up to 3 records + $1 for ever 2 records after that). PayPal goods and services is cool with us! Hope we can help you out! Happy RSD!
- Animal Collective - Prospect Hummer - $23 SOLD but have 1 more
- Mulatu Astatke - Timeless - $32
- The Backsliders - Raleighwood - $14
- John Carpenter - Village of the Damned OST - $33
- Albert Collins - Live - $32
- The Creation - In Stereo - $33
Jim Croce - You Don't Mess Around w/ Jim - $16- The Cure - Faith - $25
- Dedicated to You: Lowrider Love - $25
- Deftones - Digital Bath Picture Disc - $22
- Devo - Somewhere With - $20
- Echo and the Bunnymen - Live in Liverpool - $33
Lupe Fiasco - Food & Liquor Box - $70- Fontaines D.C. - Live - $29
- Jeffrey Dean Foster - I'm Starting to Bleed - $14
- Nubya Garcia - Source - $19
- Golden Gate Groove - Sound of Philadelphia - $26
- Groundhogs - Who Will Save the World - $32
- Gruntruck - Push - $40
- Having a Party - Sun Records - $12
- Holsapple & Stamey - Our Back Pages - $22
- I Mean Alarmed - The Toulon-Pedro Connect - $25
- Sarah Jarosz - I Still Haven't Found... - $13
- Jeezy - Thug Motivation - $33
- Bobo Jenkins - My All New Life Story - $29
- Juicy J - Hustle Continues - $36
- The Kinks - Percy - $30
- Ladies Choice - The Pen of Swan Records - $27
- The London Suede - Love & Poison - $32
Love Spit Love - Trysome Eatone - $30- Me'shell - Peace Beyond Passion - $35
- Noc
Unless specified, the following vinyl albums should be in at least NM/NM condition (media/sleeve) with the pressing in parentheses and comparable pricing based on online resources (e.g. Discogs). Please post a comment on here first before reaching out to me via chat or PM. I would prefer to ship USPS Media Mail for $5 with the possibility of combining shipping for multiple items. If you're outside CONUS, you're welcome to message me and I'll try to work something out if possible. I'm open to discuss pricing if you find anything to be unreasonable, but please do me the courtesy of communicating with me directly first as it's rather disruptive to this post if there's an ongoing disagreement taking place which is better addressed in a civil private discourse. I have done tons of deals on here as a buyer/seller so feel free to look me up if you're concerned about my B/S/T history. \*\*PLEASE put specific info in the notes portion on Paypal with your Reddit username and which records you're buying or I'm going to have a tough time figuring out what you purchased from me.\*\* Happy hunting!
a-ha - "Take on Me" (2015 RSD Exclusive Limited Edition Picture Disc) - $55 (SEALED) SOLD
Alessandro Alessandroni & Giovanni Tommaso - "Open Air Parade" (Limited Edition) - $50 (SEALED)
America - "History · America's Greatest Hits" (1978 Club Edition) - $10 (VG+/VG) SOLD
Armand Hammer - "Paraffin" (Deluxe Edition) - $95 (SEALED) PENDING
Autechre - "Garbage" (1995 UK Pressing) - $165 (VG+/VG)
Badfinger - "Straight Up" (Original '71 US Pressing) - $50 (VG+/VG)
Erykah Badu – "Back In The Day" (2003) - $15 (NM/VG+)
Erykah Badu – "Worldwide Underground" (Promo) - $25 (NM/VG+) SOLD
Syd Barrett - "Vegetable Man Where Are You?" (1987) - $80
Beach House - "7" (Limited Edition/Yellow/Gatefold) - $55 (SEALED)
Jon Benjamin - "Well, I Should Have..." (2015) - $125
Big Business - "Command Your Weather" (Limited Edition/Numbered/Gold) - $40
Big L - "Devil's Son EP (From The Vaults)" (2017) - $20 (SEALED) SOLD
Bobby Boyd Congress – "Bobby Boyd Congress" (Limited Edition/Numbered France 2011) - $65
Art Blakey & The Jazz Messengers – "Just Coolin'" (VMP) - $65 (SEALED)
Mary J. Blige – "My Life" (1994) - $40 (VG+/Generic)
Blues Magoos – "Psychedelic Lollipop" (1966 Mono) - $25 (VG+/VG+)
David Bowie – "The Rise And Fall Of Ziggy Stardust And The Spiders From Mars" (Mobile Fidelity Sound Lab/Limited Edition) - $195 (NM/V
... keep reading on reddit ➡Phil
Go post NSFW jokes somewhere else. If I can't tell my kids this joke, then it is not a DAD JOKE.
If you feel it's appropriate to share NSFW jokes with your kids, that's on you. But a real, true dad joke should work for anyone's kid.
Mods... If you exist... Please, stop this madness. Rule #6 should simply not allow NSFW or (wtf) NSFL tags. Also, remember that MINORS browse this subreddit too? Why put that in rule #6, then allow NSFW???
Please consider changing rule #6. I love this sub, but the recent influx of NSFW tagged posts that get all the upvotes, just seem wrong when there are good solid DAD jokes being overlooked because of them.
Thank you,
A Dad.
Sudden Lee
Well, toucan play at that game.
Martin Freeman, and Andy Serkis.
They also play roles in Lord of the Rings.
I guess that makes them the Tolkien white guys.
Windows
She said apple-lutely
'Eye-do'
This is my first post pls don't kill me lol.
The people in the comment section is why I love this subreddit!!
Cred once again my sis wants credit lol
HAVE (CIB, noted otherwise)
PS1
- Arcade Greatest Hits / The Atari Collection
- Area 51
- Army Men 3D
- Austin Powers Pinball
- Ball Breakers
- Blue's Big Musical
- Bottom of the 9th (Long Box)
- Boxing
- Bugs Bunny Lost in Time
- Car and Driver Grand Tour Racing
- CoolBoarders 2001
- CoolBoarders 4
- Courier Crisis
- Dave Mirra Freestyle BMX
- Descent (Long Box)
- Elmo's Letter Adventure
- Ford Racing
- G-Police
- Iron Soldier 3
- Madden 97
- Moto Racer
- Motor Toon Grand Prix
- Nagano Winter Olympics 98
- NASCAR 98
- NASCAR Heat
- NASCAR Racing
- NBA Live 98
- Need for Speed
- Patriotic Pinball
- PGA Tour 98
- Playstation Underground Jampack Fall 2001 (sealed)
- Pro Pinball Big Race USA
- Pro Pinball Fantastic Journey
- Nicktoons Racing
- RC De Go (super fun racing game!)
- Reel Fishing
- Rugrats in Paris The Movie
- Spec Ops Covert Assault
- Star Wars Episode I The Phantom Menace
- Super Bubble Pop
- Syphon Filter
- Syphon Filter 2
- The Dukes of Hazzard Racing for Home
- The Italian Job
- Thrasher: Skate and Destroy
- Tiny Toon Adventures: Plucky's Big Adventure
- Treasure of the Deep
- Triple Play 2001
- Wheel of Fortune 2nd Edition
PS2
- Capcom Fighting Evolution
- Dino Stalker (disc)
- Extermination (no manual)
- Gungriffon Blaze
- Ultimate Ninja 4: Naruto Shippuden (no manual)
- Silpheed Lost Planet
- Taz: Wanted
- The Simpsons Skateboarding
PS3
- Castlevania Lords of Shadow 2 (no manual)
- Devil May Cry HD Collection (no manual)
- FEAR 3
- Jurassic the Hunted (no manual)
- Tales of Xillia Limited Edition
- The Saboteur
- The Testament of Sherlock Holmes
- Vanquish
- Wet (custom cover, no manual)
- White Knight Chronicles
PS4
- Attack on Titan
- Daymare 1998
- Daymare 1998 Black Edition (sealed)
- Division 2 Ultimate Steelbook Edition
- Dragon Quest XI Echoes of an Elusive Age Edition Of Light
- Eve Valkyrie
- Hollow Knight (sealed + 4 DLC packs)
- NASCAR Heat 4 Gold Edition
- Paranormal Activity VR
- Radial G
- RIVE Limited Edition (sealed - Orange Variant)
- Roller Coaster Tycoon
- Shakedown Hawaii (sealed)
- Sleeping Dogs Definitive Edition w/ LE case+Artbook
- Sine Mora EX
- Street Fighter V: Champion Edition
- The Bard's Tale IV: Director's Cut
- Those Who Remain Deluxe Edition
- Warriors Orochi 4
- WRC 9
- Yomawari Midnight Shadows
PS Vita
PS Vita
- 7scarlet (w/ sealed Art Cards)
- Digimon Cyber Sleuth (Japanese Import)
- Need for
Keep in mind, my son is 4 years old, so everything is an original to him.
I had to work late into the evening yesterday, and he was just going to bed when I got home. I had left home for the office nearly 14 hours prior, had a long day, lots of meetings, traffic, etc.
When I walked through the door, I was exhausted, run down, and starving. My wife hugged me and asked how my day was, and I replied, "Done. It was a good day, but has got me exhausted. I just want to grab a bite and go to bed. I'm hungry."
From my son's bedroom, I hear him shout, "Hi Hungry! Nice to meet you!"
Not only did it make me laugh, but I completely forgot about how hungry and tired I was. I went to his bedroom, and we laughed together about it. It was exactly what I needed.
Edit: Thanks for all the awards, kind strangers! I'll let my son know y'all enjoyed his joke too!
I heard parents named their children lance a lot.
First post please don't kill me
Edit: i went to sleep and now my inbox is dead, thank you kind strangers for the awards!
Japan.
second hand stores!
it's Hans free now..
A photocatalytic system was developed for perfluoroalkylation of vinyl‐substituted all‐carbon quaternary centers by using perfluoroalkyl halides with concomitant 1,2‐aryl migration. This strategy possesses good functional‐group compatibility and can serve as a powerful synthetic tool for the construction of valuable perfluoroalkylated compounds that would be difficult to prepare by other methods.
Abstract
An efficient method for photocatalytic perfluoroalkylation of vinyl‐substituted all‐carbon quaternary centers involving 1,2‐aryl migration has been developed. The rearrangement reactions use fac‐Ir(ppy)3, visible light and commercially available fluoroalkyl halides and can generate valuable multisubstituted perfluoroalkylated compounds in a single step that would be challenging to prepare by other methods. Mechanistically, the photoinduced alkyl radical addition to an alkene leads to the migration of a vicinal aryl substituent from its adjacent all‐carbon quaternary center with the concomitant generation of a C‐radical bearing two electron‐withdrawing groups that is further reduced by a hydrogen donor to complete the domino sequence.
https://ift.tt/3bRAYh2
