Need help purifying! How do I separate out these spots that are this close? This is after running a column using 2% acetone:toluene (adding 1% triethylamine). reddit.com/gallery/nmnhut
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πŸ‘€︎ u/daddy_body23
πŸ“…︎ May 28 2021
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What grew on this triethylamine bottle? imgur.com/nU0TH1m
πŸ‘︎ 1k
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πŸ‘€︎ u/THE_CRUSTIEST
πŸ“…︎ Feb 05 2021
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TIL Scientists in China have successfully grown tooth enamel which paves the way to replace fillings & crowns. A chemical mixture applied to whole human teeth created an enamel layer 2.7 micrometers thick within 48 hours. (Calcium & phosphate ions with triethylamine in alcohol). telegraph.co.uk/science/2…
πŸ‘︎ 70k
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πŸ‘€︎ u/Miskatonica
πŸ“…︎ Jul 12 2020
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A one pot reaction: bromination with bromine followed by a cyclization through dehydrobromination using triethylamine. The little sputter from the second step startled me (too much coffee perhaps). 🀣 v.redd.it/yo0470wkjnq61
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πŸ‘€︎ u/chemnerdgirl
πŸ“…︎ Apr 02 2021
🚨︎ report
Purpose of adding triethylamine in oxalate diester formation in regards to Le Chatelier’s Principle?(Chemiluminescence lab)

I am a bit confused on the reason triethylamine is added to the phenol and oxalyl chloride in the formation of diesters to test for chemiluminescence. Thanks.

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πŸ‘€︎ u/cartistanaccount
πŸ“…︎ Feb 24 2021
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Triethylamine
πŸ‘︎ 116
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πŸ‘€︎ u/jonanncos
πŸ“…︎ Aug 18 2020
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Green solvent to remove triethylamine hydrochloride without ligand exchange?

I've got a mixture of TEA.HCL with my metal complex and want to separate the two,but can't use water or alcohols because one of the ligands on the complex exchanges with OH - any ideas? Needs to be semi-green since we're doing it on a multi-year scale

πŸ‘︎ 6
πŸ’¬︎
πŸ“…︎ Feb 18 2020
🚨︎ report
TIL Scientists in China have successfully grown tooth enamel which paves the way to replace fillings & crowns. A chemical mixture applied to whole human teeth created an enamel layer 2.7 micrometers thick within 48 hours. (Calcium & phosphate ions with triethylamine in alcohol). telegraph.co.uk/science/2…
πŸ‘︎ 2
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πŸ‘€︎ u/luzm86
πŸ“…︎ Jul 12 2020
🚨︎ report
Benzoyl peroxide + triethylamine. (full-length video tutorial in comments) v.redd.it/w049zrn5yld51
πŸ‘︎ 113
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πŸ“…︎ Jul 28 2020
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Paranoia about triethylamine exposure, can you guys reassure me?

So essentially I work with insects and occasionally I use triethylamine as a spray, like twice a week. I spray it for under 10 seconds into boxes and then open them up. When I use it I essentially either use it in a room with a ventilated fan or outdoors but I fan it out for a minute. I'm paranoid about getting cancer or something horrible from this. I suffer from anxiety too so that's why I'm reaching out, because it's embarrassing to ask my boss about it and I figure some people here could quell my fears, I'm fairly sure I'm just being paranoid.

I know it's not supposed to be inhaled but if any of you have worked with triethylamine before it has a very strong odor so I can smell it sometimes. It's strong enough that I'm reassured by that because it seems like the strong irritant effect kind of saves me from actual exposure, like because it's an irritant it smells strongly so I naturally avoid that smell. It smells very toxic though so I'm worried about getting specifically lung cancer lol. On the SDS it has the scary health hazard symbol, and I immediately think that's the carcinogen symbol every time I see it. But if you look at the SDS it's toxic and an irritant and bad to get on your skin but it's not classified as a carcinogen. I'm worried thought because it specifically says it's not classifiable as a carcinogen which makes me believe that the long term health effects haven't really been studied. Most of what I found was stuff about how acute exposure in high amounts can lead to eye issues but just temporarily. It is an airway irritant and can cause damage, but I can't tell based on the ppm what that means in terms of my own exposure.

As I was typing this post up I saw on one of the sheets that it said that repeated exposure can irritate the lungs and cause bronchitis in the long term. In the acute term it says that in higher exposures it can cause a buildup of fluid in the lungs and cause pulmonary edema and how that's a medical emergency. That's not a chronic thing right, like that's talking about not being able to breathe in the moment? I've had a chronic cough since starting this job (but rationally I think it is that I have a post-nasal drip, because it just seems to be a lot of mucous buildup in my nose/mouth area not my lungs really) and I'm super paranoid I either have lung cancer or bronchitis now. I've also noticed my chest feels pressure when I'm in a pool, whereas it didn't before. I know I get paranoid sometimes so I'm real

... keep reading on reddit ➑

πŸ‘︎ 2
πŸ’¬︎
πŸ‘€︎ u/screammcqueen
πŸ“…︎ Jul 02 2019
🚨︎ report
Triethylamine in 4mmc synth?

Alright, so i have been reading about how to increase yeilds and stuff for 4mmc. I have found a couple strange synths where they use methylamine and triethylamine in the final stage. Why is this?

Sidenote: I found a synth that litterally read like this.

”20g substrate was disolved in 100mL benzene added 20g NaOH in 100mL H2O added 40mL mehylamine (aq solv). 2h boiled with reflux Added HCl in dioxane, filtered.”

”Mildronate comments: when using hcl aq solv red shit forming washed awa with acetone. What is orginal paper (literature) for this method?”

”Anothe method from internet also writed in wiki, what is original papaer for this (literature)?:”

Just wanted to show that

πŸ‘︎ 8
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πŸ‘€︎ u/Lokdeluxe
πŸ“…︎ Oct 16 2019
🚨︎ report
TIL Scientists in China have successfully grown tooth enamel which paves the way to replace fillings & crowns. A chemical mixture applied to whole human teeth created an enamel layer 2.7 micrometers thick within 48 hours. (Calcium & phosphate ions with triethylamine in alcohol). telegraph.co.uk/science/2…
πŸ‘︎ 2
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πŸ“…︎ Jul 13 2020
🚨︎ report
Using Pyridine vs. Triethylamine

Hello Everyone!

I am a graduate student working on a phosphite reaction and the procedures for this reaction used pyridine. However, in my haste and ignorance, I accidently used triethyl amine. Is this going to be a big issue, or will triethyl amine accomplish the same goal as pyridine?

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πŸ‘€︎ u/andyhamisgay
πŸ“…︎ Feb 08 2019
🚨︎ report
PUMP selection for TEA (triethylamine) offloading

I'm trying to select a pump for triethylamine offloading. one of the requirements is that the pump has to be explosion proof.

The following is being suggested to me by licensor.

https://www.psgdover.com/docs/default-source/wilden-docs/eom/p820_p830-fit-metal-eom.pdf

http://info.sandpiperpump-idex.com/acton/attachment/17738/f-005a/1/-/-/-/-/S20S30MiniSalesSheet_web.pdf

How can i confirm that these are explosion proof?

Thank you

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πŸ‘€︎ u/Baltazar17
πŸ“…︎ Dec 14 2019
🚨︎ report
Syringe choice for triethylamine.

Hi everyone. I'm currently getting together a bunch of equipment to do some simple synthesis and have run into an issue. I will be dosing triethylamine into my flask under nitrogen but the only glass syringes that I have are 10ml and I really only need 1ml of reagent. I have some standard all polypropylene 3ml syringes (with luer locks) that I was considering using but I can't find anywhere that tells me if they are resistant to the triethylamine. What say you organic chemists?

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πŸ‘€︎ u/Gopher42
πŸ“…︎ Sep 29 2015
🚨︎ report
How does triethylamine help prevent acetal/ketal formation?
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πŸ‘€︎ u/Total_Boron
πŸ“…︎ Nov 07 2017
🚨︎ report
Triethylamine removal

So I recently converted a methoxy group to a alcohol on a compound that also had a a tertiary amine using BBr3. The compound is pretty polar so I added some triethlyamine during the flash column. The problem now is that I can't get that ET3N away from my product and its dominating my proton NMR spectra. I tried leaving it on the roto vap for awhile but that didn't do the trick.

Any techniques to get rid of the triethylamine?

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πŸ‘€︎ u/Saltine_Warrior
πŸ“…︎ Nov 13 2015
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Removing triethylamine from purified product

Ran a purification using a teledyne ISCO automated HPLC purifier on a very polar compound. Initial TLC suggested I needed to use triethylamine (TEA) in my running solvent to get the spot to move off the base line (30% MeOH in DCM did nothing, used 10% MeOH in DCM with 1% TEA). Made a 1% TEA in MeOH and DCM solvent reservoirs for the purification. Isolated my product and concentrated it but the final weight is way off by a couple 100mg (looking for ~30mg). Been trying to azeotrope the TEA off with toluene and DCM with little improvement. Any ideas or suggestions? Next thing I'm planning on trying is a manual hand column.

πŸ‘︎ 2
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πŸ‘€︎ u/Ladybiller
πŸ“…︎ Feb 07 2017
🚨︎ report
TIL Soaking fish in milk for 1hr removes all traces of fish stench. The acids in milk neutralize the bases from the triethylamine. blogs.miaminewtimes.com/s…
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πŸ‘€︎ u/zazoom783
πŸ“…︎ Mar 04 2015
🚨︎ report
Is triethylamine supposed to be fluorescent under UV?

Because the stuff in my TEA bottle is highly fluorescent and I can't find any source that confirms one way or the other.

Kind of urgent.

edit: what about pyridine? Why are all my organic bases fucking fluorescent?

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πŸ“…︎ Dec 01 2016
🚨︎ report
TLC and streaking: why add triethylamine?

In one of my labs, Et3N was added to "supposedly" prevent streaking on the TLC plates. I know it's a base and it will deprotonate my product, but I'm not sure how this affects it.

From a random website: > Compounds which possess strongly acidic or basic groups (amines orcarboxylic acids) sometimes show up on a TLC plate with this behavior.Add a few drops of ammonium hydroxide (amines) or acetic acid(carboxylic acids) to the eluting solvent to obtain clearer plates

I think this is pertinent information, not sure what to make of it...

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πŸ‘€︎ u/welovewong
πŸ“…︎ Nov 19 2013
🚨︎ report
Drying triethylamine over molecular sieves.

Hi chemists of Reddit.

A few days ago a we decided to dry and degas several organic bases by storing them over 4A molecular sieves and bubbling nitrogen through them.

Among these bases was triethylamine. At first it appeared to have worked however after one day the liquid began to turn yellow and after two days it was all a deep yellow colour.

What's gone wrong?? Our big 'Purification of Laboratory Chemicals' book even suggests drying over sieves. If anyone could help that would be fantastic!

Thanks!

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πŸ‘€︎ u/andreasinthesky
πŸ“…︎ Mar 06 2012
🚨︎ report
I've read that to separate amines on silica, it is best to add some triethylamine, and to separate carboxylic acids it is best to add some formic acid. I need to purify a compound containing an amine and two carboxylic acids. What should I use in this case?
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πŸ“…︎ Dec 15 2013
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[Research] Is triethylamine supposed to fluoresce green under UV? Kind of urgent

Need to know if my stuff is contaminated/expired and Google isn't giving me any confirmation either way.

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πŸ“…︎ Dec 01 2016
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Deactivating Silica Gel with Triethylamine

We're a group of chemical engineer students (2 semester) doing a project where we try to optimize a synthesis of 2-bromcyclohexanol by using NBS and cyclohexene. One of the ways we want to try optimizing the yield and purity is by deactivating the silica column with triethylamine. (Solvent: 5% ethylacetate/95% pentane, where the ethylacetate will have to be lowered to 3% when we deactivate using triethylamine so it won't be too polar.)

The reason we want to do this is because the silica may react as a lewis acid with our product (the hydroxyl group) and create bromocyclohexene, which would be an impurity and lower yield.

Do you think this reaction between the silica and the hydroxyl is likely? Would deactivating the silica help give us a bigger yield? Do you see something we have not considered? Any advice for when we do this or do you know a study that did something similar?

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πŸ‘€︎ u/lythya
πŸ“…︎ May 13 2015
🚨︎ report
So this is the reaction I was talking about
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πŸ‘€︎ u/froxy74
πŸ“…︎ May 25 2021
🚨︎ report
DAD JOKES ARE NOT DIRTY.

Go post NSFW jokes somewhere else. If I can't tell my kids this joke, then it is not a DAD JOKE.

If you feel it's appropriate to share NSFW jokes with your kids, that's on you. But a real, true dad joke should work for anyone's kid.

Mods... If you exist... Please, stop this madness. Rule #6 should simply not allow NSFW or (wtf) NSFL tags. Also, remember that MINORS browse this subreddit too? Why put that in rule #6, then allow NSFW???

Please consider changing rule #6. I love this sub, but the recent influx of NSFW tagged posts that get all the upvotes, just seem wrong when there are good solid DAD jokes being overlooked because of them.

Thank you,

A Dad.

πŸ‘︎ 11k
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πŸ‘€︎ u/Von_Bostaph
πŸ“…︎ Jun 18 2021
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What do you call a man with no arms or legs in a hole?

Phil

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πŸ‘€︎ u/Rumblebully
πŸ“…︎ Jun 30 2021
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Rational
πŸ‘︎ 7k
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πŸ‘€︎ u/mainhoonmadrasi
πŸ“…︎ Jun 30 2021
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My wife blocked me on Facebook because I post too many bird puns.

Well, toucan play at that game.

πŸ‘︎ 9k
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πŸ‘€︎ u/Zayan-ali
πŸ“…︎ Jun 30 2021
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There are only two white people in the movie Black Panther

Martin Freeman, and Andy Serkis.

They also play roles in Lord of the Rings.

I guess that makes them the Tolkien white guys.

πŸ‘︎ 12k
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πŸ‘€︎ u/jzagri
πŸ“…︎ Jun 24 2021
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My 3 yr old daughter made her first pun today and I almost cried. She was eating an apple and I asked her if she liked apples.

She said apple-lutely

πŸ‘︎ 12k
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πŸ“…︎ Jun 29 2021
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What did the left eye say to the right eye when they got married?

'Eye-do'

This is my first post pls don't kill me lol.

The people in the comment section is why I love this subreddit!!

Cred once again my sis wants credit lol

πŸ‘︎ 6k
πŸ’¬︎
πŸ‘€︎ u/tieyz
πŸ“…︎ Jun 27 2021
🚨︎ report
What was a very common name in the middle ages?

I heard parents named their children lance a lot.

First post please don't kill me

Edit: i went to sleep and now my inbox is dead, thank you kind strangers for the awards!

πŸ‘︎ 9k
πŸ’¬︎
πŸ“…︎ Jun 24 2021
🚨︎ report
Paranoid about triethylamine exposure, can someone reassure me?

So essentially I work with insects and occasionally I use triethylamine as a spray, like twice a week. I spray it for under 10 seconds into boxes and then open them up. When I use it I essentially either use it in a room with a ventilated fan or outdoors but I fan it out for a minute. I'm paranoid about getting cancer or something horrible from this. I suffer from anxiety too so that's why I'm reaching out, because it's embarrassing to ask my boss about it and I figure some people here could quell my fears, I'm fairly sure I'm just being paranoid.

I know it's not supposed to be inhaled but if any of you have worked with triethylamine before it has a very strong odor so I can smell it sometimes. It's strong enough that I'm reassured by that because it seems like the strong irritant effect kind of saves me from actual exposure, like because it's an irritant it smells strongly so I naturally avoid that smell. It smells very toxic though so I'm worried about getting specifically lung cancer lol. On the SDS it has the scary health hazard symbol, and I immediately think that's the carcinogen symbol every time I see it. But if you look at the SDS it's toxic and an irritant and bad to get on your skin but it's not classified as a carcinogen. I'm worried thought because it specifically says it's not classifiable as a carcinogen which makes me believe that the long term health effects haven't really been studied. Most of what I found was stuff about how acute exposure in high amounts can lead to eye issues but just temporarily. It is an airway irritant and can cause damage, but I can't tell based on the ppm what that means in terms of my own exposure.

As I was typing this post up I saw on one of the sheets that it said that repeated exposure can irritate the lungs and cause bronchitis in the long term. In the acute term it says that in higher exposures it can cause a buildup of fluid in the lungs and cause pulmonary edema and how that's a medical emergency. That's not a chronic thing right, like that's talking about not being able to breathe in the moment? I've had a chronic cough since starting this job (but rationally I think it is that I have a post-nasal drip, because it just seems to be a lot of mucous buildup in my nose/mouth area not my lungs really) and I'm super paranoid I either have lung cancer or bronchitis now. I've also noticed my chest feels pressure when I'm in a pool, whereas it didn't before. I know I get paranoid sometimes so I'm real

... keep reading on reddit ➑

πŸ‘︎ 3
πŸ’¬︎
πŸ‘€︎ u/screammcqueen
πŸ“…︎ Jul 02 2019
🚨︎ report

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