Stability of Radicals: I know that the number of alkyl groups attached to the radical increases its stability, however I got confused when the radical is not on the secondary carbons.
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︎ May 17 2021
Adjusting to secondary stability of Delta 17?
I just picked up a Delta 17, coming from a Necky Looksha 17 - a big poly bathtub with great primary that felt like it could take a tidal wave.
I'm adjusting to the low primary on the Delta, and learning to trust the secondary. I know it's a more advanced boat and excited to up my game. Any advice on how to manage what feels like wobbliness? What's the right way to play the waves?
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︎ Jun 04 2021
Class 3 rapids at βLittle Fallsβ on the St. Croix River which borders Canada and USA through New Brunswick and Maine. The Penobscot 17.4 has excellent secondary stability with a slight keel, allowing for exceptional control through fast moving water.
reddit.com/gallery/nket4x
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︎ May 25 2021
Class 3 rapids at βLittle Fallsβ on the St. Croix River which borders Canada and USA through New Brunswick and Maine. The Penobscot 17.4 has excellent secondary stability with a slight keel, allowing for exceptional control through fast moving water.
reddit.com/gallery/nket4x
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︎ May 25 2021
So i want a pistol secondary i can use to one shot people from long ranges but also have a good hipfire stability for close range needs. Any good pistols? I'm rank 51 and i have 1858 new army. Also what build with the mentioned pistol?
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︎ Nov 11 2020
Knife Gun +50 stability -30 range. Can be equipped as a secondary.
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︎ Apr 16 2020
How can I determine stability between carbocations of the same order? ( secondary , tertiary) If Iβm up to speed then IV and V are my only tertiary and primary carbacations therefore my most and least stable. How can I order the rest by stability if all 3 are secondary?
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︎ Oct 03 2020
Stability of Carbocations. Why is the second carbocation more stable than the first? The first C+ is tertiary but the second C+ is secondary. Maybe the cycloalkane strain factor is bigger than the factor of neighboring carbons?
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︎ Sep 04 2019
The Tron Foundation has announced a $20 million buyback plan in a bid to bolster community activity and market stability. The company is going to conduct the largest tron (TRX) token buyback plan so far with the widest coverage in the secondary market.
coinfi.com/news/600828/trβ¦
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︎ Jun 30 2019
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︎ Nov 30 2019
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︎ Aug 08 2018
Pen/handwriting suggestions for people with messy handwriting secondary to poor joint stability??
Another redditor suggested I post this here. Sorry for the long post. Just wanted to give some background.
Iβm in a profession where neat handwriting matters and I often have to write quickly. However, handwriting has been a challenge for me growing up because I have unstable finger and wrist joints. As a kid they always had me use pencil grips or giant pencils. Need to write in pen for work but find myself struggling to keep things legible with most pens unless I have a death grip on it and write painfully slow. Any suggestions?
Second request. Cursive always looks neater and seems faster for note taking...but due to my handwriting issues as a kid they gave up teaching it to me. I thought maybe I should start working on improving my cursive too. Suggestions for improving cursive (or handwriting in general) as well? Thanks!
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︎ Aug 20 2018
Fecal microbiota transplantation associated with 10 years of stability in a patient with secondary progressive MS (SPMS)
ncbi.nlm.nih.gov/pmc/artiβ¦
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︎ Apr 17 2018
@BlackBlueReview:"DG says this draft is the start of trying to build stability in the secondary. Doesnβt want to keep rotating CBs in and out every year."
twitter.com/BlackBlueReviβ¦
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︎ Apr 30 2016
Better wifi stability after removing secondary puck?
I've been getting connection timeouts over wi-fi recently in my living room. That is one of the secondary pucks and isn't too far from and in direct line of sight of the primary. Doing a ping test over wifi from the living room ranges from 100-1000ms and randomly drops icmp packets. After I turned off the secondary puck, ping tests improved greatly, avg 6ms pings with no packet loss. I use this puck to help provide a wired connection to some devices. I'm at a loss as to why this is. Could this be a middle zone where devices are trying to constantly hand-off between the two points? Any ideas? Thanks
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︎ Sep 30 2017
Secondary concerned about stability
Hi-- I'm a 20-something yo woman in a ten month, long distance, largely mono relationship with a woman, who has a long-term, long distance primary poly relationship of six years.
Recently, she's been having some relationship issues with her primary, and due to a lack of ability to communicate, they're on a break.
Now, I'm freaked out, and I'm having a few conflicting emotions regarding all of this.
- I'm extremely concerned that the primary does not know the full extent of my relationship. As of a few months ago, we've recognized much more stable, romantic descriptors as accurate of our relationship. My partner made her primary aware of this, but recently her primary described our relationship again in more casual terms. The primary treats me as more of a casual, nonromantic partner, asking for details about our sex life, which I'm not comfortable with my partner sharing (I'm extremely private). I'm concerned she doesn't understand the full gravity of my relationship, and with them on a break, I'm not sure how to approach this.
- Now, with the primary relationship on a break, I don't know how to act in my own secondary relationship. I'm almost on high alert, being really careful as to not settle in to anything (getting all of my partners attention, affection, being able to call whenever I want, etc). When the primary relationship re-enters, as both me and my partner are positive will happen once she is more able to communicate, I'm afraid I'm going to feel shoved to the side.
Anybody able to relate?
I'm NOT trying to get rid of the primary, I just do have romantic, monogamous tendencies and am extremely concerned about being hurt.
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︎ Jun 14 2016
H.R. 3087: To amend the Elementary and Secondary Education Act of 1965 to assure educational stability for children in foster care, and for other purposes.
Introduced: Sponsor: Rep. Danny Davis [D-IL7]
This bill was referred to the House Committee on Education and the Workforce and House Committee on Financial Services which will consider it before sending it to the House floor for consideration.
Govtrack.us Summary
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︎ Jul 17 2015
Can a secondary benzylic carbocation undergo rearrangement if it is already resonance stabilized but the rearrangement leads to a tertiary carbocation? For instance, will a hydride shift happen here to create a tertiary carbocation or is it more stable the way it is?
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︎ Oct 22 2021
It's 2042 - It's time secondary guns are stabilized and recoupled from the main Tank/Helicopter
(Title error - decoupled)
Seriously,
This is the future. When I'm aiming the secondary turret on the tank in a direction, and the driver turns the tank/main turret. It should have NO effect on my aim anymore.
This kind of stabilized control is trivial today let alone in 2042.
This isn't your grandpa's browning mounted on top of a tank anymore.
As long as the turret is still within it's work envelope, the main driver moving the machine around should have no effect on my aim.
(Not to mention removing the nausea and frustration of being a secondary gunner from a gameplay standpoint)
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︎ Oct 08 2021
Hello all, does anyone know whatβs causing this and/or how to avoid it. I have a couple business logos with an oval around the text and theyβve all been slightly off with the secondary stitch (on hats, shirts are fine) Ideas? Bad hooping, bad stabilizer, bad user? Please and thank you.
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︎ Sep 04 2021
Here's a weird thing... I was digging in one of my files looking for the data log in the subtitle track (which doesn't appear to be there, not sure if I have to enable it.) Found a secondary video track, same color, stabilized and distortion corrected. Just 1080p30. Weird... Thoughts?
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︎ Oct 11 2021
How much Maltodextrin should I use to add body to my stabilized mead in secondary?
Hey all. I have a near perfect peanut butter and jelly mead that is clearing in secondary at the moment. I'd like to bottle age it soon however it feels a little... thin? The taste is amazing but I feel like it needs a thiccer mouthfeel.
I have maltodextrin and lactose available I was just wondering what you guys think the right amount of one of those options would be to add some pleasant body to a great tasting mead without ruining it.
Thanks in advance!!
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︎ Jul 09 2021
Just finished my first production run! They are D2 steel, with stabilized cherry for one and walnut for the rest, a Scandinavian grind with a 20 degree secondary bevel. Let me know what you guys think!
reddit.com/gallery/klee09
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︎ Dec 27 2020
Give me some secondary flavor ideas! (15% abv, OB honey, stabilized)
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︎ Feb 28 2021
Just finished my first production run! They are D2 steel, with stabilized cherry for one and walnut for the rest, a Scandinavian grind with a 20 degree secondary bevel. Let me know what you guys think!
reddit.com/gallery/klehoa
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︎ Dec 27 2020
Just finished my first production run! They are D2 steel, with stabilized cherry for one and walnut for the rest, a Scandinavian grind with a 20 degree secondary bevel. Let me know what you guys think!
reddit.com/gallery/klee09
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︎ Dec 27 2020
KMS Scharfrichter (Refitted; β’β’=Previous fitting, β’=New fitting. [Primary armament: β’β’ 32cm Italy β’ 38cm2 (German) Secondary armament: β’β’ 14cm (universal) β’ 7.62cmAA (universal)] Additional refits: Stabilizers (Temporary), 3 propellers, 2 large rudders)
reddit.com/gallery/k8jcw2
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︎ Dec 07 2020
Bottling day. Anyone else have experience reusing jars? Got a grommet to fit, hopefully not too much/too little airspace. Going to compare side by side in a month, bottle to jar. FG 1.000 for 1 month aging in secondary, no white powders to stabilize.
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︎ Dec 05 2020
It was a good weekend of mead maintenance: two batches stabilized and one racked to secondary.
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︎ Jul 21 2020
Why is there a hydride shift in this reaction? I know it's to stabilize the carbocation but both carbons have secondary substitution so it shouldn't make any difference.
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︎ Nov 09 2020
T3 Hauler, Promising Economy: Goose Neck, Quad Box Wings, Block Engine, Vertical Stabilizers. Colors are Blue Primary, Cream Secondary, Light Grey Trim.
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︎ Sep 09 2020
How long do you keep your fruit in secondary before you stabilize?
I was wondering how long I can keep fruit in before it goes bad or harms the product
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︎ May 27 2020
10.5lbs of fresh, frozen Cotton Candy Grapes and pectic enzyme. I'll mash them tonight and bag the mash to squeeze the juice out. Tomorrow it gets 71b, fermaid-o and enough Orange Blossom honey to get to 1.130. Once finished mostly dry, I'll rack to secondary, stabilize and rest on more grapes
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︎ Oct 03 2019
Racked to secondary without stabilizing
I had a 1.120 SG in a bucket for two weeks. I racked to secondary too early at 1.050. two weeks later I racked to try and clear some of the yeast and sediment. It was 1.030.
I want to maintain some of the natural sweetness, not taking it to dry. Should I stabilize it now? Will letting the secondary bottle continue to sit without stabilizing introduce poor flavors? How should I proceed?
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︎ Oct 30 2019
Can anyone help me arrange the ff. set of carbocations in order of increasing stability.
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︎ Jan 16 2022
a canoe for two adults and a child + gear for one to two nights?
I am looking to buy a canoe for next summer that can carry two adults and a child with gear for a night or two. Can you guys help, what size should the canoe be? Preferably 3 seats (2 will be fine as I can always make one as long as there is space) , not massively heavy so I may be able to lift it on cars roofrack on my own too.
What else should I consider when buying a canoe?
Any model recommendations are welcome!
My budget is not massive, so just basic family canoes with good bang for buck value are what i am looking for.
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︎ Jan 11 2022
Jerkin it with Gherkinit PPT, New Gamma Girl fire, and Daily Charting for 1.26.22
S15e10
Good Morning Everyone!
So some new stuff today before market open I wanted to point out some weird shit that went down with the SPY yesterday. This trade happened yesterday at 09:48:39 I still can't figure out the exchange source possibly BATS and Gemini but I could be wrong, anyway here is the order.
https://preview.redd.it/e0i1bsbz91e81.png?width=829&format=png&auto=webp&s=ffc4a95587f4049e9ac34c51fa69d4ac027b78c6
Which caused this
https://preview.redd.it/xy9sbpv2a1e81.png?width=1440&format=png&auto=webp&s=039f86166ae54dde7cc12ca9d1f23c4c3836163a
And that reminded me of this https://www.investopedia.com/terms/p/plunge-protection-team.asp
Yelyah2's Latest
\"The DN has dropped to $106, and seems like it acted a lot like the ceiling today, and the delta sensitivity spike grew\"
\"This one has more volatility indicators layered on, so includes the Vega neutral, and has the 30-day skew/kurtosis on the secondary axis, which has both dipped below zero. One has gone below zero in a few of the dips before an increase, but notably the last time both were below zero was back in February. Call OI % has increased to 54% after the large put expiration last Friday. Last time it was this high was 10/30/2020, on 1/12 before that initial squeeze, the call oi was only up to 48%\"
SPY
\"Right now, a 10% increase in the SPY price would lead to an extra 350m in total gamma/delta/vega combined to hedge, or ~4x the 30-day volume of 87.6m (it was 6x the 30-day volume on 1/21). Last time the sensitivity tests for hedging the SPY were this high was 12/1/21, 9/30/21, 3/4/21, 1/29/21,10/30/20, which were all right at the lows\"
TLDR by me;
Delta sensitivity continues up while the Delta Neutral breakpoint is dropping, Call OI has increased quite a bit since Friday's put expiration and skew is trending bullish, and now higher than it was last January. The options market on the SPY looks ready for a bounce.
Cycle Snapshot
T
...
keep reading on reddit β‘
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︎ Jan 26 2022
H.R. 5876: To amend the Elementary and Secondary Education Act of 1965 to provide educational stability for children in foster care, and for other purposes.
Sponsor: Rep. Danny Davis [D-IL7]
This bill is in the first stage of the legislative process. It was introduced into Congress on May 31, 2012. It will typically be considered by committee next.
Govtrack.us Summary
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︎ Jun 01 2012
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